2-氰基-3-取代胺基(或甲硫基)-3-(2-氯-5-吡啶甲胺基)-丙烯酸酯类化合物的合成及生物活性

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2-氰基-3-取代胺基(或甲硫基)-3-(2-氯-5-吡啶甲胺基)-丙烯酸酯类化合物的合成及生物活性

赵毅刚, 刘昕, 黄润秋, 程慕如, 李在国

文章导航 > 农药学学报 > 1999 > 1(1): 93-95

赵毅刚, 刘昕, 黄润秋, 程慕如, 李在国. 2-氰基-3-取代胺基(或甲硫基)-3-(2-氯-5-吡啶甲胺基)-丙烯酸酯类化合物的合成及生物活性[J]. 农药学学报, 1999, 1(1): 93-95.

引用本文:

赵毅刚, 刘昕, 黄润秋, 程慕如, 李在国. 2-氰基-3-取代胺基(或甲硫基)-3-(2-氯-5-吡啶甲胺基)-丙烯酸酯类化合物的合成及生物活性[J]. 农药学学报, 1999, 1(1): 93-95.

Zhao Yi-gang, Liu Xin, Huang Run-qiu, Cheng Mu-ru, Li Zai-guo. SYNTHESIS AND BIOLOGICAL ACTIVITY OF 3- (SUBSTITUTED) AMINO (OR METHYLTHIO)-3-(2-CHLORO- 5-PYRIDYLMETHYL) AMINO-2-CYANOACRYLATE[J]. Chinese Journal of Pesticide Science, 1999, 1(1): 93-95.

Citation:

Zhao Yi-gang, Liu Xin, Huang Run-qiu, Cheng Mu-ru, Li Zai-guo. SYNTHESIS AND BIOLOGICAL ACTIVITY OF 3- (SUBSTITUTED) AMINO (OR METHYLTHIO)-3-(2-CHLORO- 5-PYRIDYLMETHYL) AMINO-2-CYANOACRYLATE[J]. Chinese Journal of Pesticide Science, 1999, 1(1): 93-95.

赵毅刚, 刘昕, 黄润秋, 程慕如, 李在国. 2-氰基-3-取代胺基(或甲硫基)-3-(2-氯-5-吡啶甲胺基)-丙烯酸酯类化合物的合成及生物活性[J]. 农药学学报, 1999, 1(1): 93-95.

引用本文:

赵毅刚, 刘昕, 黄润秋, 程慕如, 李在国. 2-氰基-3-取代胺基(或甲硫基)-3-(2-氯-5-吡啶甲胺基)-丙烯酸酯类化合物的合成及生物活性[J]. 农药学学报, 1999, 1(1): 93-95.

Zhao Yi-gang, Liu Xin, Huang Run-qiu, Cheng Mu-ru, Li Zai-guo. SYNTHESIS AND BIOLOGICAL ACTIVITY OF 3- (SUBSTITUTED) AMINO (OR METHYLTHIO)-3-(2-CHLORO- 5-PYRIDYLMETHYL) AMINO-2-CYANOACRYLATE[J]. Chinese Journal of Pesticide Science, 1999, 1(1): 93-95.

Citation:

Zhao Yi-gang, Liu Xin, Huang Run-qiu, Cheng Mu-ru, Li Zai-guo. SYNTHESIS AND BIOLOGICAL ACTIVITY OF 3- (SUBSTITUTED) AMINO (OR METHYLTHIO)-3-(2-CHLORO- 5-PYRIDYLMETHYL) AMINO-2-CYANOACRYLATE[J]. Chinese Journal of Pesticide Science, 1999, 1(1): 93-95.

2-氰基-3-取代胺基(或甲硫基)-3-(2-氯-5-吡啶甲胺基)-丙烯酸酯类化合物的合成及生物活性

1.
南开大学元素有机化学研究所及元素有机化学国家重点实验室,天津300071

基金项目:

国家自然科学重点基金资助课题,No.2 9832 0 50

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- 文章访问数: 1400
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- PDF下载量: 413
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出版历程

SYNTHESIS AND BIOLOGICAL ACTIVITY OF 3- (SUBSTITUTED) AMINO (OR METHYLTHIO)-3-(2-CHLORO- 5-PYRIDYLMETHYL) AMINO-2-CYANOACRYLATE

1.
Institute and State Key Laboratory of Elemento Organic Chemistry

- 2-氯-5-吡啶甲胺基 /
- 丙烯酸酯 /
- 氰基 /
- 生物活性
Abstract: In this paper, 3-(2-chloro-5-pyridylmethyl)amino-2-cyano-3-methylthio ethyl acrylates 3 were synthesized. By the reaction of 3 as an intermediate with amines, 5 new 3-(substituted)amino-3-(2-chloro-5-pyridylmethyl)amino-2-cyano ethyl acrylates were prepared. When 3 reacted with hydrazine, the corresponding cyclic compound 4f was obtained. The preliminary bioassays showed that compounds 3 has good herbicidal activity.
- 2-chloro-5-pyridylmethylamino /
- cyano /
- ethyl acrylate /
- biological activity

参考文献(4)

　赵毅刚, 黄润秋, 程慕如等, 高等学校化学学报, 1998, 19 (10) : 1620

　Tom izaw aM. , Yamamo to I. J. Pest ic. Sci. ( Int. Ed. ) , 1993, 18 (1) : 91

　Huppatz J. L. , M cFadden H. G. , HuberM arie2L uise, et al. Synthesis and Chem isrty of A grochem icals III, Yo rk: M ap le P ress, 1992: 187

　王肖君, 黄志镗, 化学学报, 1989, 47: 890

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文章访问数: 1400
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PDF下载量: 413
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