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Hydantocidin及其立体异构体的合成和生物活性研究进展

王进敏 匡宇 韩金涛 金淑惠 王明安

王进敏, 匡宇, 韩金涛, 金淑惠, 王明安. Hydantocidin及其立体异构体的合成和生物活性研究进展[J]. 农药学学报, 2009, 11(1): 1-12.
引用本文: 王进敏, 匡宇, 韩金涛, 金淑惠, 王明安. Hydantocidin及其立体异构体的合成和生物活性研究进展[J]. 农药学学报, 2009, 11(1): 1-12.
WANG Jin-min, KUANG Yu, HAN Jin-tao, JIN Shu-hui, WANG Ming-an. Progress on the Synthesis and Activity of Hydantocidin and it's Isomers[J]. Chinese Journal of Pesticide Science, 2009, 11(1): 1-12.
Citation: WANG Jin-min, KUANG Yu, HAN Jin-tao, JIN Shu-hui, WANG Ming-an. Progress on the Synthesis and Activity of Hydantocidin and it's Isomers[J]. Chinese Journal of Pesticide Science, 2009, 11(1): 1-12.

Hydantocidin及其立体异构体的合成和生物活性研究进展

基金项目: 

国家自然科学基金资助项目(20772150);国家高技术研究发展计划("863"计划)资助项目(2006AA10A209).

Progress on the Synthesis and Activity of Hydantocidin and it's Isomers

  • 摘要: 在前文总结了Hydantocidin新型类似物研究进展的基础上,对Hydantocidin及其15个立体异构体、硫代Hydantocidin和碳环衍生物的合成,以及它们的除草活性等方面的研究进展进行了综述。
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    WANG Jin-min(王进敏),HAN Jin-tao(韩金涛),KUANG Yu(匡宇),et al.(新型Hydantocidin类似物的研究进展[J].Chin J Pestic Sci(农药学学报),2008,9(4): 392-403.
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    MIO S,KUMAGANA Y,SUGAI S.Synthetic Studies on (+)-hydantocidin.III.A New Synthetic Method for Construction of the Spiro-hydantoin Ring at the Anomeric Position of D-Ribofuranose[J].Tetrahedron,1991,47: 2133-2144.
    a.MATSUMOTO M,KIRIHARA M,YOSHINO T,et al.A Novel Biogenetic Type Synthesis of (+)-Hydantocidin[J].Tetrahedron Lett,1993,34: 6289-6292. b.NAKAJIMA N,MATSUMOTO M,KIRIHARA M,et al.Novel Synthesis of (+)-Hydantocidin Based on the Plausible Biosynthetic Pathway[J].Tetrahedron,1996,52: 1177-1194. c.NAKAJIMA N,KIRIHARA M,MATSUMOTO M,et al.One-step Synthesis of (-)-5-epi-Hydantocidin[J].Heterocycles,1996,42: 503-508.
    a.CHEMLA P.Stereoselective Synthesis of (+)-Hydantocidin[J].Tetrahedron Lett,1993,34: 7391-7394. b.FRUEH T,CHEMLA P,EGRHER J,et al.Natural Products as Pesticides: Two Examples of Stereoselective Synthesis[J].Pestic Sci,1996,46: 37-47. c.CHEMLA P.Preparation of (+)-Hydantocidin Derivatives as Synthons for 1,1'-Disubstituted and 1'-Spironucleosides: US 5641882 .1997-06-24. d.CHEMLA P.Stereocontrolled Preparation of (+)-Hydantocidin 1'-Spironucleosides .US 5714599.1998-02-03.
    MIRZA S.Herbicidal Ribose Spirohydantoins: DE 4129728 .1992-03-12.
    HARRINGTON P M,JUNG M E.Stereoselective Bromination of Ribofuranosyl Amide.Enantioselective Synthesis of (+)-Hydantocidin[J].Tetrahedron Lett,1994,35: 5145-5148.
    DONDONI A,SCHEMANN M C,MARRA A,et al.A General Synthetic Route to Anomeric-Azido and -Amino Acids and Formal Synthesis of (+)-Hidantocidin[J].J Org Chem,1994,59: 7517-7520.
    a.SHIOZA湋慉氠潍朮?潹普?卨灥楳物潳栠祯摦愠湈瑹潤楡湮?乯畣捩汤敩潮猠楡摮敤嬠?崭??敔浨?呯數瑯牨慹桤敡摮牴潯湣??敩浮??????????????????????扒牥?孥??嵣?值??? ̄听′儰?倱夬丳?‵区???匷???吰伮丠???坈??敚流?敉琠?愮汓??整浨??卥祳渠瑯桦攠獈楹獤?潮晴??慩牤扩潮挠祡据汤椠捃??礭摔慨湩瑯潸捯楨摹楤湡獮?癯楣慩?剩敮杛楊潝献攼汥敭挾瑃楡癲敢?慮湨摹??楡慴獥琠敒牥敳潥?獲散汨攼振瑥業瘾攬′倰栰漲猬瀳栳椷渺攬??愷琷愭氲礰稸攸搮???社捛氱漱慝搠摡椮瑆楁潉湒獂?瑎潋????敊琬框祏汒敄渠敐栠祓搬慗湁瑔潋楉湎猠孄?嵊??敥浭???传牡杬??桥敭派??敹浮???びど???て????????????扯牣?孤??崠????????刾??匯????????剳坥?????????敥浴?敡瑨?慤汲??攠浌???礼搯慥湭琾漬挱椹搹椳測??愺?倳漳猲猷椭戳氳攳‰倮爠潢栮敆牁扉楒捂楁摎敋??湁栠楊戬楆瑌楅湅杔?假甠牗椠湊攮??楮潴獨祥湳瑩桳攠獯楦猠‵愭瑅?瑩桨敹?卡楮瑴敯?潩晤??搠敦湲祯汭漠猼略捭挾楄渼愯瑥敭 ̄匭祒湩瑢桯敳瑥慛獊敝嬮?嵥??敔浥?偲敡獨瑥楤捲??椼漯捥桭放洬?倹根礵猬椵漱氺??攸洸?????????? ̄????ㄠ????扏爠?嬬?え嵉?十?????????十啉?剓???乭??乴???嘼?坥??吮?剹卮???坴??攠浓?敵瑤?慥汳??敮洠???搭效湹祤污潮獴畯捣捩楤湩慮琮敉?匮祁湬瑤桯敬琠慁獤敤??卩楯瑮攠?潰晰??捡瑣楨潥湳?潔景??祲摤愠湴瑨潥挠楓摴楥湲?慯??楯捭牥潲扳椠慯汦?倨栫礩琭潈瑹潤硡楮湴孯?嵩??敮浛?偝氮愼湥瑭 ̄偔桥祴獲楡潨汥??敯浮?????????????????????戱爳?嬮㈠?崮?慉??体丬乖??偁??匬呈?前?剒??????? ̄健?圠?剬?????攮浓?敮瑴?慥汴??攠浓??呤桩敥??潯摮攠?漫昩??捹瑤楡潮湴?慣湩摤?瑮栮敉?匮瑓特畮捴瑨略牳敩?漠景?愠??敥牲扥楯捩楳摯敭?楲湳??潦洠瀨氫攩砭?睹楤瑡桮??瑣獩?呩慮牛杊敝琮???椾湔摥楴湲条?潥晤??据琼椯癥慭琾攬搱??礱搬愴渷琺漠挲椱搴椵渭′琱漵?琮格敢??敛攱搳扝愠捓歁?剏攠杈甬汍慉瑏椠潓測?卉楔瑁敇?潗晁??搬攼湥祭氾潥獴甠捡捬椼港慥瑭放?卓祹湮瑴桨敥瑳慩獳攠孯?崠??敩浲?側牨潩捯?乹慤瑡汮??捩慮搠?卮捡楬?啧即???攠浈??????????????????????扲??佥啤?婯???匯???????刵伬????????昳昭攱挲琵漷爲献?潢晲 ̄瑛栱攴?匠瑌牁楍湂杅敒湔瑈?剃攬獂灌潁湒獅敒?呓愮牃杯敮瑣?瑳桥攠??捰瑲楯癡散?匠楴瑯攠?漭晔??敡浨??獡据桴敯牣楩捤桩楮慛?捝漮氼楥??敓浹???摥整湩祣氠潃獯畭捭捵楮湩慣瑡整?卯祮湳琼栯敥瑭愾猬攱嬹?崶??收洺??‵?椸漱??桢敲派??攵浝???????㈠??????こ??????ぁ??挠???乥?唾???噡?娼?佥啭 ̄央??佥割婥??呯??慲癯楬瑬慥瑤椠潓湹?慴獨?慳??攠捯桦愠湓楰獩浲?潤晩?卹畤扲獯瑵牲慡瑣敩??楎獵捣牬楥浯楳湩慤瑥楛潊湝?戼祥??摔敥湴祲污潨獥畤捲捯楮渺愠瑁敳?卭祭湥瑴桲敹琼愯獥敭猾嬬?崹??攬洵??椲漲挳栳攭洲椲猴琰爮礠??敓流??㈠え??????????か??????ㄠ?????搾???乡?匼???>.Stereocontrolled Synthesis of Spirosuccinimide Derivative of Hydantocidin.Tetrahedron,1995,51: 1387-1394.
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  • 收稿日期:  2008-11-02

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