二硫代氨基甲酸盐类(DTCs)杀菌剂残留分析方法综述

马婧玮; 潘灿平; 张 玲; 张军锋

二硫代氨基甲酸盐类(DTCs)杀菌剂残留分析方法综述

1.
河南省农业科学院农业质量标准与检测技术研究中心,郑州 450002
2.
中国农业大学理学院,北京 100193

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出版历程
- 收稿日期: 2009-06-11

Research progress on residue analysis of dithiocarbamates(DTCs) fungicide

1.
Center of Quality Standards & Testing Technology for Agriculture, Henan Academy ofAgricultural Sciences, Zhengzhou 450002, China
2.
College of Sciences, China Agricultural University, Beijing 100193, China

摘要

摘要: 综述了二硫代氨基甲酸盐类(DTCs)杀菌剂及其代谢物的残留分析研究现状,并对当前主要的残留分析方法如分光光度法、气相色谱法、液相色谱法及液相色谱-质谱联用技术和毛细管电泳法进行了较为详细的比较、分析,对DTCs类杀菌剂残留分析方法的未来发展进行了展望。衍生化液相色谱法虽然操作步骤较繁琐、耗时长,但结果稳定可靠,并能区分不同结构类型,是目前重点且被广泛采用的方法,而同时测定DTCs类杀菌剂母体及其代谢物的串联质谱方法将是今后进一步研究的热点课题。
- 二硫代氨基甲酸盐(DTCs) /
- 杀菌剂 /
- 残留分析 /
- 检测
Abstract: The analysis methods of dithiocarbamates(DTCs) fungicide and their metabolites, including detailed discussion of individual analysis methods, such as spectrophotometry, gas chromatography, liquid chromatography, liquid chromatography-mass spectrometry and micellar electrokinetic chromatography, etc. were reviewed. The prospects of application on the residue analysis of DTCs were predicted. Currently, high performance liquid chromatography (HPLC) determination with derivation is becoming the most applicable method, with its time-consuming, in several steps but good precision and reliability, plus with resolution for 3 different types of DTCs. It’ s expected that the simultaneous determination of dithiocarbamate fungicides matrix and their metabolites with tandem mass spectroscopy would be an active hotspot in this field.
- dithiocarbamates (DTCs) /
- fungicide /
- residues analysis /
- determination

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